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Definition 2024


silanyl

silanyl

English

Noun

silanyl (plural silanyls)

  1. Synonym of silyl
    • 2015 July 1, Rainer Zitz et al., “Neutral “Cp-Free” Silyl-Lanthanide(II) Complexes: Synthesis, Structure, and Bonding Analysis”, in Inorganic Chemistry, volume 54, DOI:10.1021/acs.inorgchem.5b01072:
      The THF complexes LnI 2 ·(THF) 2 [Ln = Yb (yellow), Eu (dark yellow), Sm (dark blue)] were prepared by reaction of small pieces of metal with 1,2-diiodoethane in THF. 32 , 33 The dark blue SmI 2 ·(THF) 2 was either dissolved in THF or suspended in toluene and treated with silanyl mono- or dianions.